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  • 695718 - (R)-3,3′-Bis(9-anthracenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphos...

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(R)-3,3′-Bis(9-anthracenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

695718 -

95%

DOWNLOAD MSDS (PDF)

Synonym: (11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

  • CAS Number: 361342-51-0

  • Empirical Formula (Hill Notation): C48H29O4P

  • Molecular Weight: 700.72

(R)-3,3′-Bis(9-anthracenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 95%
#

Properties

Related CategoriesAsymmetric Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Phosphoric Acids
assay95%
mp288-292 °C (D)

Description

Application

Catalyst used in asymmetric direct alkylation of α-diazoester via C-H bond cleavage.1

Catalysts used in enantioselective condensation/amine addition reactions

Packaging

100, 500 mg in glass btl

Protocols & Applications

Reductive Amination using BINOL-Derived Chiral Phosphoric Acids

Price and Availability


Documents

Certificate of Analysis

Structure Search
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Safety Information

SymbolGHS07  GHS07
Signal wordWarning
Hazard statementsH315-H319-H335
Precautionary statementsP261-P305 + P351 + P338
Personal Protective Equipmentdust mask type N95 (US), Eyeshields, Gloves
Hazard CodesXi
Risk Statements36/37/38
Safety Statements26
WGK Germany3
Technical information & documentation associated with this product is available in the Safety & Documentation tab.

Related Content

Chiral Phosphoric Acids: New Organocatalysts for Reductive Amination

Introduction BINOL-derived phosphoric acids have been frequently appearing in literature as useful organocatalysts. These compounds are capable of catalyzing a range of interesting processes: reducti...

References

1. Uraguchi, D.; Sorimachi, K.; Terada, M. J. Am. Chem. Soc. 127, 9360, (2005) Abstract

Rueping, M. et al. Angew. Chem. Int. Ed. Engl. 48, 908, (2009)


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